Where did you get your tyre advice? Sounds like you've been seriously misled by someone.
You shouldn't be running 205/45 on the rear of an SW20 at all. The car is designed to have a staggered tyre set-up with 195's (as standard) or 205's (very commonly) on the front and 225's on the rear.
Whatever you run, the rolling diameter also needs to be within 20mm of the standard factory setup specification (in NSW at least) if you want to be legal. You can find the standard tyre specs for your car's year by looking on Carsales at an MR2 listing for the same year.
Any tyre place that told you that running the wrong (and smaller) size on the rear should be soundly spanked.
You should also be running CORRECTLY FITTING wheels nuts AND concentric hubrings with the R32 rims, so that you rims are correctly located on the hubs. These are the correct size rings for R32 Skyline rims:
http://www.ebay.com.au/itm/Hub-Centric-Rings-OD-66-1mm-ID-60-1mm-Aluminium-Alloy-/181530974280?hash=item2a4416d848:m:m_-Z5NRD1xvoGclE8ZNoKOw I wouldn't be driving around any curvy roads until you have all that sorted out. You could break your wheel studs, end up with wobbly wheels… or much worse.
Don't compromise on safety when it comes to wheels and tyres. It just isn't worth risking your life for – or anyone else's! Also, if you have a crash, your insurance company will not cover you with the wrong size wheels and tyres.