I may be encroaching on sacred territory here, but I recommend an article on brakes called "Pulp Friction", published by Grassroots Motorsports, which clears up a whole bunch of things about braking. A link to some jpegs of the article is given below, but it is easily found elsewhere on the web too.
There is much more to improved braking than simply upgrading to 4 pots calipers or using bigger discs. For instance, I was about to embark on a popular upgrade to Mazda 4 pots with big disk etc. on another car I own, but fortunately read this first and then ran the numbers. Turns out my braking force would have been within a few percent of factory spec due to a combination of different piston sizes, center point of the clamping force on the rotor etc. I would have needed bigger wheels to fit it in, and loads of cash to do it all. The only improvement I would have gained by this upgrade (apart from street cred) was greater ability to absorb heat, which I don't need a lot of on a street car anyway (racing is another matter of course). So in the end I didn't do it and saved a lot of money, some unsprung weight, and no doubt grief fitting them.
Heat issues aside, the number 1 way to improve braking is actually to fit better tyres, as they are the bits that do the stopping. Changing to six-pot calipers and the biggest vented, slotted and cross drilled discs you can fit won't help a bit if you're running skinny tyres made from rock hard compound. Often what people perceive as improved braking actually comes down to different pedal feel. That's not necessarily a bad thing either. The brakes on one car I have bite far too soon, and on another too late, so I'd like to change them both! But, if you can lock your wheels up (ignoring ABS of course), you've obviously got enough clamping force on the disc for the tyres fitted.
The article is close to the bottom of this page:
http://www.myturbodiesel.com/1000q/brake_FAQ.htm I'm not trying to rain on anyone's parade or start a flame war; I think big brakes look good too, and if that in itself is enough reason for someone to choose to upgrade then I say go for it. Understanding the physics of how braking works might save you some money and aggravation though, so if you are interested, have a read.