Not if it was running a fully useable ign advance curve on 95 (or 98). The ECU will only apply the ign advance levels programmed into the existing ign map.
According to my calculations 80/20 is approx ~104 RON. So if the estimate on 95 above is accurate, then 91 would require approx 30% to make 100 RON.
From what I know, some fuel senders have been reported as sending erronious fuel levels on E85, but this seems to be a particular type of sender, and may be from the increased conductivity of the fuel, as much as the fuel itself.